Biodiesel synthesis and kinetic analysis based on MnCO3/Na-silicate as heterogeneous catalyst

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Yanan Zhang
Hui Liu
Xiaochan Zhu
Ivana Lukić
http://orcid.org/0000-0001-6406-5813
Miodrag Zdujić
Xiang Shen
Dejan Skala

Abstract

Тhe MnCO3/Na silicate (Mn/Na/Si mole ratio of 4.65:1:1.65) catalyst in the form of solid particles with diameter of 0.99–1.99 mm was used as a catalyst for transesterification of soybean oil in batch autoclave at different conditions: 388–468 K, methanol-to-oil mole ratio 12:1–30:1, catalyst amount based on the mass of oil 012.5 %. The complete triacylglycerols (TAG) conversion and high yield of fatty acid methyl ester (FAME) was obtained after 1 h at 458 K, methanol-to-oil mole ratio 30:1 and 10 % of catalyst. Kinetics of transesterification process was analyzed by three models: the simple first order irreversible reaction rate, as well as two more complex models recently rep­orted in literature. The catalyst reuse in transesterification process was tested and the average values of 99.0 % of TAG conversion and 97.5 % of FAME yield were obtained after 8 consecutive runs. Different techniques were used to characterize fresh and used MnCO3/Na silicate catalyst. The determined amounts of leached Na (<500 ppm) and Mn (<20 ppm) in biodiesel phase implied that the homogeneous-heterogeneous process influences the catalyst selectivity, whereby leached Na enables the complete transformation of TAG to FAME.

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How to Cite
[1]
Y. Zhang, “Biodiesel synthesis and kinetic analysis based on MnCO3/Na-silicate as heterogeneous catalyst”, J. Serb. Chem. Soc., vol. 83, no. 3, pp. 345–365, Apr. 2018.
Section
Chemical Engineering

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