Investigation of Bi2O3-rich part of Bi2O3–PbO phase diagram

Aleksandra Dapčević, Dejan Poleti, Ljiljana Karanović, Jelena Miladinović

Abstract


A new Bi-rich part of Bi2O3 - PbO phase diagram was determined using differential thermal analysis and X-ray powder diffraction techniques. Four solid solutions, α‑Bi2O3, γ‑Bi2O3, δ-Bi2O3 and βss-Bi8Pb5O17, can be distinguished below 37.5 mol% of PbO and one compound, β2-Bi8Pb5O17. Two of them, δ-Bi2O3 and βss-Bi8Pb5O17 are high-temperature phases. The large field of γ‑Bi2O3 stability was implemented making the crucial difference comparing to phase diagrams from the Bi2O3 - PbO system published so far.

Keywords


Bi2O3; PbO; phase diagram

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DOI: http://dx.doi.org/10.2298/JSC170711111D

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