Signal amplification for sumatriptan sensing based on polymeric surface decorated with Cu nanoparticles

Ghasem Karim-Nezhad, Samane Khanaliloo, Zeynab Khorablou, Parisa Seyed Dorraji

Abstract


A new nanocomposite (Cu NPs/poly melamine) was deposited on glassy carbon electrode by cyclic voltammetry. Uniform deposition of the nanocomposite was observed by field emission scanning electron microscopy. The electron transfer characteristics of sumatriptan (SUM), was greatly improved on the modified electrode. The prepared electrode was used for sensitive determination of SUM by differential pulse voltammetry. Linear calibration curve was obtained in the concentration ranges of 0.08 - 0.58 and 0.58 6.5 μM, and detection limit of 0.025 µM. The proposed method was evaluated by determination of SUM in human biological fluids such as urine and blood plasma with satisfactory results (recovery > 99 %).

Keywords


sumatriptan; melamine; glassy carbon electrode; copper nanoparticles; differential pulse voltammetry.

Full Text:

PDF (1,857 kB)

References


C. M. Villalon, D. Centurion, L. F. Valdivia, P. de Vries, P. R. Saxena, Curr. Vasc. Pharmacol. 1 (2003) 71

K. Ahonen, M. L. Hamalainen, H. Rantala, K. Hoppu, Neurology 62 (2004) 883

E. Fuseau, O. Petricoul, K. H. Moore, A. Barrow, T. Ibbotson, Clin. Pharmacokin. 41 (2002) 801

M. W. Pierce, Neurotherapeutics 7 (2010) 159

B. K. Ramu, K. Raghubabu, Int. J. Pharm. Biomed. Sci. 1 (2010) 49

A. Avadhanulu, J. Srinivas, Y. Anjaneyulu, Indian Drugs 33 (1996) 334

D. Tipre, P. Vavia, Indian Drugs 36 (1999) 501

J. Oxford, M. Lant, J. Chromatogr., B 496 (1989) 137

K. Vishwanathan, MG. Bartlett, JT. Stewart, Rapid Commun. Mass Spectrom. 14 (2000) 168

A. Tan, P. Hang, J. Couture, S. Hussain, F. Vallée, J. Chromatogr., B 856 (2007) 9

J. J. Seo, J. Park, M. H. Bae, M.-S. Lim, S. J. Seong, J. Lee, S. M. Park, H. W. Lee, Y.-R. Yoon, J. Chromatogr., B 919 (2013) 38

M. Dunne, P. Andrew, J. Pharm. Biomed. Anal. 14 (1996) 721

C. Saka, Ö. Şahin, Crit. Rev. Anal. Chem. 43 (2013) 2

C. Saka, Crit. Rev. Anal. Chem. 39 (2009) 32

A. Femenía-Font, V. Merino, V. Rodilla, A. López-Castellano, J. Pharm. Biomed. Anal. 37 (2005) 621

Z. Ge, E. Tessier, L. Neirinck, Z. Zhu, J. Chromatogr. B 806 (2004) 299

M. Franklin, J. Odontiadis, E. Clement, J. Chromatogr. B 681 (1996) 416

K. Altria, J. Chromatogr. A 735 (1996) 43

M. B. Gholivand, L. Mohammadi-Behzad, J. Electroanal. Chem. 712 (2014) 33

L. Torkian, N. Mohammadi, E. Amereh, Middle East J. Sci. Res. 14 (2013) 754

M. Amiri, Z. Pakdel, A. Bezaatpour, S. Shahrokhian, Bioelectrochemistry 81 (2011) 81

S. Shahrokhian, Z. Kamalzadeh, R-S. Saberi, Electrochim. Acta 56 (2011) 10032

M. Ghalkhani, S. Shahrokhian, F. Ghorbani-Bidkorbeh, Talanta 80 (2009) 31

B. J. Sanghavi, P. K. Kalambate, S. P. Karna, A. K. Srivastava, Talanta 120 (2014) 1

A. Safavi, N. Maleki, F. Tajabadi, E. Farjami, Electrochem. Commun. 9 (2007) 1963

A. N. Shipway, M. Lahav, I. Willner, Adv. Mater. 12 (2000) 993

D. N. Muraviev, Contributions to Science 3 (2005) 19

Y. Ohnuki, H. Matsuda, T. Ohsaka, N. Oyama, J. Electroanal. Chem. 158 (1983) 55

S. Tian, J. Liu, T. Zhu, W. Knoll, Chem. Mater. 16 (2004) 4103

R. Davies, G. A. Schurr, P. Meenan, R. D. Nelson, H. E. Bergna, C. A. Brevett, R. H. Goldbaum, Adv. Mater. 10 (1998) 1264

L. Zhang, M. Wan, J. Phys. Chem., B 107 (2003) 6748

X. Liu, L. Luo, Y. Ding, Q. Wu, Y. Wei, D. Ye, J. Electroanal. Chem. 675 (2012) 47

D. Hai-Yun, Z. Ye, S-J. Zhang, Y. Xue-Bo, L. Yi-Jun, H. Xi-Wen, Chin. J. Anal. Chem. 36 (2008) 839

E. Laviron, J. Electroanal. Chem. 10 (1979) 19.




DOI: http://dx.doi.org/10.2298/JSC170727006K

Refbacks

  • There are currently no refbacks.

Comments on this article

View all comments


Copyright (c) 2018 J. Serb. Chem. Soc.

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

IMPACT FACTOR 0.822 (131 of 166 journals)
5 Year Impact Factor 1.015 (118 of 166 journals)