%PDF-1.6
%
1 0 obj
<<
/AcroForm 2 0 R
/Metadata 3 0 R
/Names 4 0 R
/OCProperties <<
/D <<
/AS [5 0 R 6 0 R 7 0 R]
/ON [8 0 R]
/Order []
/RBGroups []
>>
/OCGs [8 0 R 9 0 R]
>>
/PageLabels 10 0 R
/Pages 11 0 R
/Type /Catalog
>>
endobj
12 0 obj
<<
/Author (Zhou, Su-Qin and Xia, Qi-Ying and Liang, Meng and Ju, Xue-Hai)
/CreationDate (D:20210226104312+01'00')
/Creator (PScript5.dll Version 5.2.2)
/ModDate (D:20210226111135+01'00')
/Producer (Acrobat Distiller 9.0.0 \(Windows\))
/Title ({Study on charge mobility of hexathiapentacene and its selenium analogs})
/bibtex#2FISSN (0352-5139)
/bibtex#2FDOI (10.2298/jsc200511045z)
/bibtex#2FPAGES (171--180)
/bibtex#2FJOURNAL (J. Serb. Chem. Soc.)
/bibtex#2FNUMBER (02)
/bibtex#2FURL (https://www.shd-pub.org.rs/index.php/JSCS/article/view/9498)
/bibtex#2FKEY_FIELD (Zhou2021)
/bibtex#2FPUBLISHER (Serbian Chemical Society)
/Keywords (ambipolar,density functional theory,hopping mechanism,organic semiconductor,selenium substitution)
/bibtex#2FMONTH (feb)
/bibtex#2FVOLUME (86)
/Subject (The relationship between molecular geometries, crystal structures and charge mobilities of hexathiapentacene \(HTP\) and its three derivatives \(2Se-HTP, 4Se-HTP, 6Se-HTP\) were studied with density functional theory combined with hopping mechanism in the molecular and crystal level. The effect of Se substitution on the charge mobility was discussed. The calculated results showed that the derivatives exhibit good planarity and the molecular geometries have little variation during the charge transfer process. The electron mobility is 1.20 cm2 V?1 S?1 for HTP and 2.30 cm2 V?1 S?1 for 6Se-HTP, which are much larger than the corresponding hole ones, indicating that HTP and 6Se-HTP are good candidates for n-type organic semiconductor. However, 2Se-HTP and 4Se-HTP have comparable hole and electron mobilities and are suitable for ambipolar semiconductor.nema)
/bibtex#2FYEAR (2021)
/bibtex#2FFILE (:C\\:/Users/Dekanski/AppData/Local/Mendeley Ltd./Mendeley Desktop/Downloaded/Zhou et al. - 2021 - Study on charge mobility of hexathiapentacene and its selenium analogs.pdf:pdf;:D\\:/OneDrive/02_SHD-WEB/JSCS/Vol86/JSCS_No2_2021_www/06_9498_5413.pdf:PDF)
/bibtex#2Fentrytype (Article)
>>
endobj
2 0 obj
<<
/DA (/Helv 0 Tf 0 g )
/DR <<
/Encoding <<
/PDFDocEncoding 13 0 R
>>
/Font <<
/Helv 14 0 R
/ZaDb 15 0 R
>>
>>
/Fields []
>>
endobj
3 0 obj
<<
/Length 4170
/Type /Metadata
/Subtype /XML
>>
stream
2021-02-26T10:43:12+01:00
PScript5.dll Version 5.2.2
2021-02-26T11:11:35+01:00
2021-02-26T11:11:35+01:00
Acrobat Distiller 9.0.0 (Windows)
uuid:3af4e998-edb9-4669-bb6f-de86fd30e557
uuid:a021ed96-08fc-4e44-a757-13f6e7c8d8c1
The relationship between molecular geometries, crystal structures and charge mobilities of hexathiapentacene (HTP) and its three derivatives (2Se-HTP, 4Se-HTP, 6Se-HTP) were studied with density functional theory combined with hopping mechanism in the molecular and crystal level. The effect of Se substitution on the charge mobility was discussed. The calculated results showed that the derivatives exhibit good planarity and the molecular geometries have little variation during the charge transfer process. The electron mobility is 1.20 cm2 V?1 S?1 for HTP and 2.30 cm2 V?1 S?1 for 6Se-HTP, which are much larger than the corresponding hole ones, indicating that HTP and 6Se-HTP are good candidates for n-type organic semiconductor. However, 2Se-HTP and 4Se-HTP have comparable hole and electron mobilities and are suitable for ambipolar semiconductor.nema
Su-Qin Zhou
Qi-Ying Xia
Meng Liang
Xue-Hai Ju
bibtex/bibtexkey/Zhou2021
bibtex/file/:C\:/Users/Dekanski/AppData/Local/Mendeley Ltd./Mendeley Desktop/Downloaded/Zhou et al. - 2021 - Study on charge mobility of hexathiapentacene and its selenium analogs.pdf:pdf;:D\:/OneDrive/02_SHD-WEB/JSCS/Vol86/JSCS_No2_2021_www/06_9498_5413.pdf:PDF
bibtex/issn/0352-5139
bibtex/journal/J. Serb. Chem. Soc.
bibtex/month/feb
bibtex/number/02
bibtex/pages/171--180
bibtex/url/https://www.shd-pub.org.rs/index.php/JSCS/article/view/9498
bibtex/volume/86
10.2298/jsc200511045z
ambipolar
density functional theory
hopping mechanism
organic semiconductor
selenium substitution
Serbian Chemical Society
{Study on charge mobility of hexathiapentacene and its selenium analogs}
2021-02
application/pdf
Article
endstream
endobj
4 0 obj
<<
/EmbeddedFiles 16 0 R
>>
endobj
5 0 obj
<<
/Category [/View]
/Event /View
/OCGs [8 0 R]
>>
endobj
6 0 obj
<<
/Category [/Print]
/Event /Print
/OCGs [8 0 R]
>>
endobj
7 0 obj
<<
/Category [/Export]
/Event /Export
/OCGs [8 0 R]
>>
endobj
8 0 obj
<<
/Name (Watermark)
/Type /OCG
/Usage <<
/Export <<
/ExportState /ON
>>
/PageElement <<
/Subtype /FG
>>
/Print <<
/PrintState /ON
>>
/View <<
/ViewState /ON
>>
>>
>>
endobj
9 0 obj
<<
/Name (Headers/Footers)
/Type /OCG
/Usage <<
/PageElement <<
/Subtype /HF
>>
>>
>>
endobj
10 0 obj
<<
/Nums [0 17 0 R]
>>
endobj
11 0 obj
<<
/Count 10
/Kids [18 0 R]
/Type /Pages
>>
endobj
13 0 obj
<<
/Differences [24 /breve /caron /circumflex /dotaccent /hungarumlaut /ogonek /ring /tilde 39
/quotesingle 96 /grave 128 /bullet /dagger /daggerdbl /ellipsis /emdash /endash
/florin /fraction /guilsinglleft /guilsinglright /minus /perthousand /quotedblbase /quotedblleft /quotedblright /quoteleft
/quoteright /quotesinglbase /trademark /fi /fl /Lslash /OE /Scaron /Ydieresis /Zcaron
/dotlessi /lslash /oe /scaron /zcaron 160 /Euro 164 /currency 166
/brokenbar 168 /dieresis /copyright /ordfeminine 172 /logicalnot /.notdef /registered /macron
/degree /plusminus /twosuperior /threesuperior /acute /mu 183 /periodcentered /cedilla /onesuperior
/ordmasculine 188 /onequarter /onehalf /threequarters 192 /Agrave /Aacute /Acircumflex /Atilde
/Adieresis /Aring /AE /Ccedilla /Egrave /Eacute /Ecircumflex /Edieresis /Igrave /Iacute
/Icircumflex /Idieresis /Eth /Ntilde /Ograve /Oacute /Ocircumflex /Otilde /Odieresis /multiply
/Oslash /Ugrave /Uacute /Ucircumflex /Udieresis /Yacute /Thorn /germandbls /agrave /aacute
/acircumflex /atilde /adieresis /aring /ae /ccedilla /egrave /eacute /ecircumflex /edieresis
/igrave /iacute /icircumflex /idieresis /eth /ntilde /ograve /oacute /ocircumflex /otilde
/odieresis /divide /oslash /ugrave /uacute /ucircumflex /udieresis /yacute /thorn /ydieresis]
/Type /Encoding
>>
endobj
14 0 obj
<<
/BaseFont /Helvetica
/Encoding 13 0 R
/Name /Helv
/Subtype /Type1
/Type /Font
>>
endobj
15 0 obj
<<
/BaseFont /ZapfDingbats
/Name /ZaDb
/Subtype /Type1
/Type /Font
>>
endobj
16 0 obj
<<
/Kids [19 0 R]
>>
endobj
17 0 obj
<<
/S /D
/St 171
>>
endobj
18 0 obj
<<
/Count 10
/Kids [20 0 R 21 0 R 22 0 R 23 0 R 24 0 R 25 0 R 26 0 R 27 0 R 28 0 R 29 0 R]
/Parent 11 0 R
/Type /Pages
>>
endobj
19 0 obj
<<
/Limits [ ]
/Names [ 30 0 R]
>>
endobj
20 0 obj
<<
/Contents 31 0 R
/CropBox [0 0 595.22 842]
/MediaBox [0 0 595.22 842]
/Parent 18 0 R
/Resources <<
/ColorSpace <<
/CS0 [/Indexed /DeviceCMYK 255 32 0 R]
/CS1 [/Indexed /DeviceCMYK 15 33 0 R]
>>
/ExtGState <<
/GS0 34 0 R
/GS1 35 0 R
>>
/Font <<
/C2_0 36 0 R
/C2_1 37 0 R
/TT0 38 0 R
>>
/ProcSet [/PDF /Text /ImageC /ImageI]
/XObject <<
/Fm0 39 0 R
/Fm1 40 0 R
/Fm2 41 0 R
/Fm3 42 0 R
/Im0 43 0 R
/Im1 44 0 R
>>
>>
/Rotate 0
/Type /Page
>>
endobj
21 0 obj
<<
/Contents 45 0 R
/CropBox [0 0 595.22 842]
/MediaBox [0 0 595.22 842]
/Parent 18 0 R
/Resources <<
/ExtGState <<
/GS0 34 0 R
/GS1 46 0 R
>>
/Font <<
/C2_0 36 0 R
/TT0 38 0 R
/TT1 47 0 R
>>
/ProcSet [/PDF /Text /ImageB]
/XObject <<
/Fm0 48 0 R
/Fm1 49 0 R
/Fm2 50 0 R
/Im0 51 0 R
/Im1 52 0 R
/Im10 53 0 R
/Im11 54 0 R
/Im12 55 0 R
/Im13 56 0 R
/Im14 57 0 R
/Im15 58 0 R
/Im16 59 0 R
/Im17 60 0 R
/Im18 61 0 R
/Im19 62 0 R
/Im2 63 0 R
/Im3 64 0 R
/Im4 65 0 R
/Im5 66 0 R
/Im6 67 0 R
/Im7 68 0 R
/Im8 69 0 R
/Im9 70 0 R
>>
>>
/Rotate 0
/Type /Page
>>
endobj
22 0 obj
<<
/Contents 71 0 R
/CropBox [0 0 595.22 842]
/MediaBox [0 0 595.22 842]
/Parent 18 0 R
/Resources <<
/ExtGState <<
/GS0 34 0 R
/GS1 72 0 R
>>
/Font <<
/C2_0 36 0 R
/C2_1 73 0 R
/C2_2 74 0 R
/T1_0 75 0 R
/TT0 38 0 R
>>
/ProcSet [/PDF /Text]
/XObject <<
/Fm0 76 0 R
/Fm1 77 0 R
/Fm2 78 0 R
>>
>>
/Rotate 0
/Type /Page
>>
endobj
23 0 obj
<<
/Contents 79 0 R
/CropBox [0 0 595.22 842]
/MediaBox [0 0 595.22 842]
/Parent 18 0 R
/Resources <<
/ExtGState <<
/GS0 34 0 R
/GS1 80 0 R
>>
/Font <<
/C2_0 36 0 R
/C2_1 73 0 R
/C2_2 37 0 R
/C2_3 74 0 R
/T1_0 75 0 R
/TT0 38 0 R
>>
/ProcSet [/PDF /Text]
/XObject <<
/Fm0 81 0 R
/Fm1 82 0 R
/Fm2 83 0 R
>>
>>
/Rotate 0
/Type /Page
>>
endobj
24 0 obj
<<
/Contents 84 0 R
/CropBox [0 0 595.22 842]
/MediaBox [0 0 595.22 842]
/Parent 18 0 R
/Resources <<
/ExtGState <<
/GS0 34 0 R
/GS1 85 0 R
>>
/Font <<
/C2_0 36 0 R
/C2_1 74 0 R
/TT0 38 0 R
>>
/ProcSet [/PDF /Text /ImageC]
/XObject <<
/Fm0 86 0 R
/Fm1 87 0 R
/Fm2 88 0 R
/Im0 89 0 R
/Im1 90 0 R
/Im2 91 0 R
/Im3 92 0 R
>>
>>
/Rotate 0
/Type /Page
>>
endobj
25 0 obj
<<
/Contents 93 0 R
/CropBox [0 0 595.22 842]
/MediaBox [0 0 595.22 842]
/Parent 18 0 R
/Resources <<
/ExtGState <<
/GS0 34 0 R
/GS1 94 0 R
>>
/Font <<
/C2_0 36 0 R
/C2_1 74 0 R
/TT0 38 0 R
>>
/ProcSet [/PDF /Text /ImageC]
/XObject <<
/Fm0 95 0 R
/Fm1 96 0 R
/Fm2 97 0 R
/Im0 98 0 R
>>
>>
/Rotate 0
/Type /Page
>>
endobj
26 0 obj
<<
/Contents 99 0 R
/CropBox [0 0 595.22 842]
/MediaBox [0 0 595.22 842]
/Parent 18 0 R
/Resources <<
/ExtGState <<
/GS0 34 0 R
/GS1 100 0 R
>>
/Font <<
/C2_0 36 0 R
/C2_1 37 0 R
/C2_2 74 0 R
/TT0 38 0 R
>>
/ProcSet [/PDF /Text]
/XObject <<
/Fm0 101 0 R
/Fm1 102 0 R
/Fm2 103 0 R
>>
>>
/Rotate 0
/Type /Page
>>
endobj
27 0 obj
<<
/Contents 104 0 R
/CropBox [0 0 595.22 842]
/MediaBox [0 0 595.22 842]
/Parent 18 0 R
/Resources <<
/ExtGState <<
/GS0 34 0 R
/GS1 105 0 R
>>
/Font <<
/C2_0 36 0 R
/C2_1 106 0 R
/C2_2 107 0 R
/TT0 38 0 R
/TT1 108 0 R
/TT2 109 0 R
>>
/ProcSet [/PDF /Text]
/XObject <<
/Fm0 110 0 R
/Fm1 111 0 R
/Fm2 112 0 R
>>
>>
/Rotate 0
/Type /Page
>>
endobj
28 0 obj
<<
/Contents 113 0 R
/CropBox [0 0 595.22 842]
/MediaBox [0 0 595.22 842]
/Parent 18 0 R
/Resources <<
/ExtGState <<
/GS0 34 0 R
/GS1 114 0 R
>>
/Font <<
/C2_0 36 0 R
/C2_1 115 0 R
/C2_2 37 0 R
/TT0 38 0 R
>>
/ProcSet [/PDF /Text]
/XObject <<
/Fm0 116 0 R
/Fm1 117 0 R
/Fm2 118 0 R
>>
>>
/Rotate 0
/Type /Page
>>
endobj
29 0 obj
<<
/Contents 119 0 R
/CropBox [0 0 595.22 842]
/MediaBox [0 0 595.22 842]
/Parent 18 0 R
/Resources <<
/ExtGState <<
/GS0 34 0 R
/GS1 120 0 R
>>
/Font <<
/C2_0 36 0 R
/C2_1 115 0 R
/C2_2 37 0 R
/TT0 38 0 R
>>
/ProcSet [/PDF /Text]
/XObject <<
/Fm0 121 0 R
/Fm1 122 0 R
/Fm2 123 0 R
>>
>>
/Rotate 0
/Type /Page
>>
endobj
30 0 obj
<<
/EF <<
/F 124 0 R
>>
/F (Press Quality.joboptions)
/Type /Filespec
/UF
>>
endobj
31 0 obj
<<
/Length 4688
/Filter /FlateDecode
>>
stream
HWYoG~ׯGra> DEql6biM9@~ሱh3!vpA1/8S~Xx=߆og|Zk9WnCb/nŀfI Bwοȇ뇳W|%K&Sn>I3Ө(=68&8꙽f6o?QuVnTdxM
B34
/+A1EHH;(u"kE1%
|\pknv[?}'\x$g^89YC9c]Y(/`Rhh0$X@@N[-1w& RMAQٗↅ#1
6+%NOB
`uoK`g
g4IkpT{:AVq3tFw.z:+e~GVie?Y1W%$˲+;ƀlX$/hd1J\FKuF38cZ
z%(|đ|)MR,Z%F;"̂Α4nRpB^Tg/$*#<;vDFxP
'a0PS7 ;y_H2*=GpNb@0cfTRvY1s=N%3)Fjdf0Z31)Qe_}tJ59]ZY;al=,M7~vt>Qj{/qs#NnV|[xvy8l>}ppv>}7oT42x>?>>}쁉2j
s;eDnlB&>$Ʒ_~!Gvd`id7ۻ
1'RIA%|bn~;;Os1kU,$P`3"Q;t) H$Uk,%pה(%*SQz J8`6خ,KEh$>! "TS%?GF*|M%a\aqC+]kj+<
[bhRi˪mrvpUfr+vEӅ2buBB:2ŝ"B\L邠ae nzxD0IEa@YH$7yˌ8}<`Yxpb.!*C3wfu-I%+
JuL(8
bȢWbF}R)m3Ef:2@SuBV&H<ӉK T/NL{1(/r)F|Ij#v