Synthesis and characterization of Fe3O4/PEG-400/oxalic acid magnetic nanoparticles as a heterogeneous catalyst for the synthesis of pyrrolin-2-ones derivatives Scientific paper

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Published: Nov 22, 2021
Updated: 22.11.2021
DOI: https://doi.org/10.2298/JSC210521059E
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Iron (II) Iron (III) oxide nanocomposite catalyst pyrrolin-2-one MCR green chemistry

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Seyran Esmailzadeh
Department of Chemistry, Faculty of Sciences, Mahabad Branch, Islamic Azad University, Mahabad, Iran
Davood Setamdideh
Department of Chemistry, Faculty of Sciences, Mahabad Branch, Islamic Azad University, Mahabad, Iran
https://orcid.org/0000-0003-4608-9322

Abstract

In this study, oxalic acid was successfully loaded onto Fe3O4/PEG-400 under ultrasonic irradiation and Fe3O4/PEG/oxalic acid as a new nanomagnetic catalyst was synthesized. The chemical structure of the catalyst was investigated by the FT-IR, XRD, EDX and SEM methods. The catalyst was used for the syn­thesis of 3-acyl-5-hydroxy-3-pyrrolin-2-one derivatives from the corresponding aldehydes, anilines and dimethyl acetylenedicarboxylate (DMAD) by a one-pot and three-component MCR reaction in the excellent yields (90–95 %) of products within 24 h at room temperature. Fourteen samples are available. The recovered catalyst could be satisfactorily used for a second and third run without regener­ation. This method has a green and eco-friendly profile. In addition, this research introduces an improved mechanism for these types of reaction. The chemical structures of new compounds was characterized by their FT-IR, 1H-NMR, 13C-NMR and mass spectra.

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[1]
S. Esmailzadeh and D. Setamdideh, “Synthesis and characterization of Fe3O4/PEG-400/oxalic acid magnetic nanoparticles as a heterogeneous catalyst for the synthesis of pyrrolin-2-ones derivatives: Scientific paper”, J. Serb. Chem. Soc., vol. 86, no. 11, pp. 1039–1052, Nov. 2021.
Issue
Vol. 86 No. 11 (2021)
Section
Inorganic Chemistry
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