Transport properties of binary liquid mixtures – Candidate solvents for optimized flue gas cleaning processes
Main Article Content
Abstract
Thermal conductivities and viscosities of three pure chemicals, monoethanolamine (MEA), tetraethylene glycol dimethyl ether (TEGDME) and polyethylene glycol 200 (PEG 200) and two binary mixtures (MEA+
+TEGDME and MEA+PEG 200) were measured at six temperatures: 298.15, 303.15, 308.15, 313.15, 318.15 and 323.15 K and atmospheric pressure. Measurement of the thermal conductivities was based on a transient hot wire measurement setup, while the viscosities were measured with a digital Stabinger SVM 3000/G2 viscometer. From these data, deviations in the thermal conductivity and viscosity were calculated and fitted to the Redlich–Kister equation. Thermal conductivities of mixtures were correlated using the Filippov, Jamieson, Baroncini and Rowley models, while the viscosity data were correlated with the Eyring-UNIQUAC, Eyring-NRTL and McAlister models.
Downloads
Metrics
Article Details
Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution license 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
References
A. Aroonwilas, A. Veawab, Ind. Eng. Chem. Res. 43 (2004) 2228
E. F. da Silva, H. F. Svendsen, Ind. Eng. Chem. Res. 45 (2006) 2497
E. F. da Silva, H. F. Svendsen, Ind. Eng. Chem. Res. 43 (2004) 3413
J.-G. Shim, J.-H. Kim, Y. H. Jhon, J. Kim, K.-H. Cho, Ind. Eng. Chem. Res. 48 (2009) 2172
B. R. Strazisar, R. R. Anderson, C. M. White, Energ. Fuel 17 (2003) 1034
J. K. Carson, K. N. Marsh, A. E. Mather, J. Chem. Thermodyn. 32 (2000) 1285
M. Heisel, A. Belloni, Gas. Sep. Pur. 5 (1991) 111
C. N. Schubert, W. I. Echter, CN Patent 1364096A (2002)
F. Murrieta-Guevara, E. Rebolledo-Libreros, A. Trejo, J. Chem. Eng. Data 37 (1992) 4
F. Murrieta-Guevara, A. Trejo, J. Chem. Eng. Data 29 (1984) 456
O. Redlich, A. T. Kister, Ind. Eng. Chem. 40 (1948) 345
B. E. Poling, J. M. Prausnitz, J. P. OConnell, The Properties of Gasses and Liquids, 5th ed., McGraw–Hill, New York, 2001
D. T. Jamieson, J. B. Irving, J. S. Tudhope, Liquid Thermal Conductivity. A Data Survey to 1973, H. M. Stationary Office, Edinburgh, 1975
C. Baroncini, P. DiFilippo, G. Latini, M. Pacetti, Thermal Conductivity, 17th ed., Plenum Pub., New York, 1983
R. L. Rowley, Chem. Eng. Sci. 43 (1988) 361
L. T. Novak, Ind. Eng. Chem. Res. 43 (2004) 2602
R. J. Martins, M. J. E. D. Cardoso, O. E. Barcia, Ind. Eng. Chem. Res. 39 (2000) 849
R. A. McAllister, AIChE J. 6 (1960) 427
T. G. Amunsden, L. E. Oi, D. A. Eimer, J. Chem. Eng. Data 54 (2009) 3096
R. M. DiGullio, W. L. McGregor, A. S. Teja, J. Chem. Eng. Data 37 (1992) 242
Y. Maham, C.-N. Liew, A. E. Mather, J. Sol. Chem. 31 (2002) 743
S. Asnavez, M. E. Ferreyra de Ruiz Holgado, E. L. Arancibia, J. Mol. Liq. 124 (2006) 78
M. E. Ferreyra de Ruiz Holgado, C. R. de Schaefer, E. L. Arancibia, J. Chem. Eng. Data 47 (2002) 144
A. Pal, G. Dass, A. Kumar, J. Chem. Eng. Data 44 (1999) 2
R. Burgdorf, A. Zocholl, W. Arlt, H. Knapp, Fluid Phase Equilib. 164 (1999) 225
S. Ottani, D. Vitalini, F. Comelli, C. Castellari, J. Chem. Eng. Data 47 (2002) 1197
https://www.dynalene.com/v/vspfiles/templates/210/datasheets/Dynalene_PEG_Series_Technical_Data_Sheet.pdf (05.06. 2016)
Y. Nagasaka, A. Nagashima, J. Phys., E: Sci. Instrum. 14 (1981) 1435
H. S. Carslow, J. C. Jaeger, Conduction of Heat in Solids, Oxford University Press, Oxford, 1959
M. Kostic, K. C. Simham, in Proceedings of 6th WSEAS International Conference on Heat and Mass Transfer, Ningbo, China, 2009, p. 71
Evaluation of measurement data – Guide to the expression of uncertainty in measure¬ment, Joint Committee for Guides in Metrology, 2008
D. Salavera, K. R. Patil, A. Coronas, J. Chem. Eng. Data 55 (2010) 1449
J.-H. Song, S.-B. Park, J.-H. Yoon, H. Lee, J. Chem. Eng. Data 41 (1996) 1152
R. M. DiGuilio, R.-J. Lee, S. T. Schaeffer, L. L. Brasher, A. S. Teja, J. Chem. Eng. Data 37 (1992) 239
X. Esteve, F. Olive, K. R. Patil, S. K Chandhari, A. Coronas, Fluid Phase Equilib. 110 (1995) 369
F. Olive, K. R. Patil, J. Fernandez, A. Coronas, Thermochim. Acta 259 (1995) 57.