Reaction of a 3-aryilidene-2-thiohydantoin derivative with polymeric trans-[CuCl2(DMSO)2]n complex: unexpected isomerization to dinuclear cis-[{CuCl(DMSO)2}(mi-Cl)]2

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Petar B. Stanić
Marko V. Rodić
Tanja V. Soldatović
Aleksandar B. Pavić
Nataša S. Radaković
Biljana M. Šmit
http://orcid.org/0000-0001-9799-4723
Marija D. Živković
https://orcid.org/0000-0002-1467-8002

Abstract

The 3-arylidene-2-thiohydantoin derivative, 3-[(2-hydroxy­benzyl­idene)amino]-2-thioxoimidazolidin-4-one, was synthesized in a two-step con­densation reaction of 2-hydroxybenzaldehyde, thiosemicarbazide and ethyl chloroacetate. The ligand was structurally characterized by NMR and IR spec­troscopy, as well as by elemental analysis. In the reaction of the well-known polymeric trans-[CuCl2(DMSO)2]n complex with the polydentate thiohydan­toin type ligand, instead of the corresponding copper thiohydantoin complex, unexpectedly, the dinuclear cis-[{CuCl(DMSO)2}(m-Cl)]2 complex (1) was formed predominantly as the final stable product. The structure of the complex 1 was confirmed by single crystal X-ray diffraction analysis. The cis-complex is obtained through assisted isomerization of the trans-form, in which the thio­hydantoin derivative has a crucial role.

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How to Cite
[1]
P. B. Stanić, “Reaction of a 3-aryilidene-2-thiohydantoin derivative with polymeric trans-[CuCl2(DMSO)2]n complex: unexpected isomerization to dinuclear cis-[{CuCl(DMSO)2}(mi-Cl)]2”, J. Serb. Chem. Soc., vol. 85, no. 12, pp. 1591–1603 , Dec. 2020.
Section
Inorganic Chemistry

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