TY - JOUR AU - Keškić, Tanja AU - Radanović, Dušanka AU - Pevec, Andrej AU - Turel, Iztok AU - Gruden, Maja AU - Andjelkovic, Katarina AU - Mitić, Dragana AU - Zlatar, Matija AU - Čobeljić, Božidar PY - 2020/10/30 Y2 - 2024/03/29 TI - Synthesis, X-ray structure and DFT calculation of magnetic properties of binuclear Ni(II) complex with tridentate hydrazone-based ligand JF - Journal of the Serbian Chemical Society JA - J. Serb. Chem. Soc. VL - 85 IS - 10 SE - Inorganic Chemistry DO - 10.2298/JSC200625038K UR - https://www.shd-pub.org.rs/index.php/JSCS/article/view/9641 SP - 1279–1290 AB - <p class="Abstract">Binuclear double end-on azido bridged Ni(II) complex (<strong>1</strong>) with com­position [Ni2<strong>L</strong>2(<em>μ</em>-1,1-N3)2(N3)2]×6H2O, (<strong>L</strong> = (<em>E</em>)-<em>N</em>,<em>N</em>,<em>N</em>-trimethyl-2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-amin) was synthesized and cha­racterized by single-crystal X-ray diffraction method. Ni(II) ions are hexa­coor­dinated with the tridentate heteroaromatic hydrazone-based ligand and three azido ligands (one terminal and two are end-on bridges). DFT calcul­at­ions revealed that coupling between two Ni(II) centers is ferromagnetic in agreement with binuclear Ni(II) complexes with similar structures.</p> ER -