Homogeneous microwave-assisted carboxymethylation from totally chlorine free bleached olive tree pruning residues pulp Scientific paper

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Imen Landolsi
https://orcid.org/0000-0002-9992-0178
Narjes Rjiba
https://orcid.org/0000-0002-3431-8661
Mohamed Hamdaoui
https://orcid.org/0000-0002-3561-7081
Omar Anis Harzallah
https://orcid.org/0000-0002-4693-2570
Chedly Boudokhane
https://orcid.org/0000-0003-4593-001X

Abstract

This study deals with a new methodology for the production of car­boxymethyl cellulose (CMC) from olive pruning residues, agricultural by-pro­ducts. Cellulose was extracted by the soda–anthraquinone pulping process, and the pulp bleaching was performed using totally chlorine free (TCF) bleaching. Then, CMC microwave-assisted synthesis was performed in a homogeneous media, using DMA/LiCl as a cellulose solvent. A Box–Behnken design was applied in order to evaluate which parameters of the carboxymethylation pro­cess (viz. reaction time, reaction temperature, and amount of monochloroacetic acid) affect the degree of substitution and the yield of the synthesis reaction of this cellulose derivative. Optimized conditions to yield CMC were determined based on the desirability function approach. The prepared materials under syn­thesis using the optimal conditions were characterized using several analytical tools, i.e., FTIR, TGA, DSC and SEM. This cellulose derivative was success­fully fabricated by a fast and efficient microwave-assisted method and thus would provide many opportunities for diverse applications.

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How to Cite
[1]
I. Landolsi, N. Rjiba, M. Hamdaoui, O. A. Harzallah, and C. Boudokhane, “Homogeneous microwave-assisted carboxymethylation from totally chlorine free bleached olive tree pruning residues pulp: Scientific paper”, J. Serb. Chem. Soc., vol. 87, no. 2, pp. 247–261, Sep. 2021.
Section
Polymers

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