Cobalt catalyzed defunctionalization reactions: Review article

LJiljana Koračak; Vladimir Ajdačić

doi:10.2298/JSC240315045K

PDF (3.13 MB)

Published: Apr 9, 2024

DOI: https://doi.org/10.2298/JSC240315045K

Keywords:

decarbonylation decarboxylation dehalogenation desulfurization deoxygenation

LJiljana Koračak

Innovative Centre, Faculty of Chemistry, Ltd. Studentski Trg 12-16, 11158 Belgrade, Serbia

https://orcid.org/0000-0003-4892-1290

Vladimir Ajdačić

Vladimir Ajdačić Faculty of Chemistry, University of Belgrade, 11000 Belgrade, Serbia E-mail: ajdacic@chem.bg.ac.rs

https://orcid.org/0000-0002-3423-0862

Abstract

Catalytic defunctionalization of complex molecules has attracted significant attention in organic synthesis. This reaction enables common functional groups to serve as "traceless handles" for the new bond construction. In this mini-review, we have summarized the latest advances, methodologies and mechanistic insights into the selective cleavage of C-C and C-X bonds catalyzed by cobalt complexes, shedding light on their increasing importance in modern chemical synthesis. The content of this review is categorized according to the type of functional group being removed from molecules.

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How to Cite

[1]

L. Koračak and V. Ajdačić, “Cobalt catalyzed defunctionalization reactions: Review article”, J. Serb. Chem. Soc., Apr. 2024.

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Accepted Manuscripts

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Organic Chemistry

This work is licensed under a Creative Commons Attribution 4.0 International License.

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution license 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

Funding data

Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja
Grant numbers 451-03-66/2024-03/200288

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Cobalt catalyzed defunctionalization reactions Review article