Kinetics and mechanism of the oxidation of dithiocarbamic acids in the presence of Co(II) phthalocyaninetetacarboxylic acid

Main Article Content

Artur Vashurin
http://orcid.org/0000-0003-2239-8753
Ilya Kuzmin
Vladimir Mayzlish
Mikhail Razumov
Oleg Golubchikov
Oscar Koifman

Abstract

The present work contains kinetic data of the oxidation of sodium diethyldithiocarbamate in the presence of phthalocyanine catalysts. It is shown that the nature of the peripheral substituent has a great influence on the self-
-association of phthalocyanines and on their catalytic activity. A mechanism of the oxidation of sodium diethyldithiocarbamate involving the formation of a triple complex of the substrate, the reduced form of the catalyst and oxygen is offered. It is also shown that the oxidation mechanism of dithiocarbamic acids is different from that for cysteine.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

Article Details

How to Cite
[1]
A. Vashurin, I. Kuzmin, V. Mayzlish, M. Razumov, O. Golubchikov, and O. Koifman, “Kinetics and mechanism of the oxidation of dithiocarbamic acids in the presence of Co(II) phthalocyaninetetacarboxylic acid”, J. Serb. Chem. Soc., vol. 81, no. 9, pp. 1025–1036, Oct. 2016.
Section
Physical Chemistry
Author Biographies

Artur Vashurin, Ivanovo State University of Chemistry and Technology, Ivanovo 153000, Russia and Research Institute of Macroheterocycles of Ivanovo State University of Chemistry and Technology, Ivanovo 153000, Russia

Ph.D., Senior Reseacher, assistant professor, Department of Inorganic Chemistry

Ilya Kuzmin, Ivanovo State University of Chemistry and Technology, Ivanovo 153000, Russia

Master Student

Vladimir Mayzlish, Ivanovo State University of Chemistry and Technology, Ivanovo 153000, Russia

Professor

Mikhail Razumov, Research Institute of Macroheterocycles of Ivanovo State University of Chemistry and Technology, Ivanovo 153000

Master Student

Oleg Golubchikov, Ivanovo State University of Chemistry and Technology, Ivanovo 153000, Russia

Professor

Oscar Koifman, Research Institute of Macroheterocycles of Ivanovo State University of Chemistry and Technology, Ivanovo 153000

Head, Professor

References

A. B. Sorokin, Chem. Rev. 113 (2013) 8152

B. Basu, S. Satapathy, A. K. Bhatnagar, Catal. Rev. 35 (1993) 571

A. Shaabani, K. Keshipour, M. Hamidzad, S. Shaabani, J. Mol. Catal., A: Chem. 395 (2014) 494

M. Mirzaeian, A. M. Rashidi, M. Zare, R. Ghabezi, J. Nat. Gas Sci. Eng. 18 (2014) 439

Z. Huang, H. Bao, Y. Yao, W. Lu, W. Chen, Appl. Catal., B 154–155 (2014) 36

T. Billard, B. R. Langlois, S. Large, D. Anker, N. Roidot, P. Roure, J. Org. Chem. 61 (1996) 7545

B. Banerjee, S. N. Chakravarty, B. V. Kamath, A. B. Biswas, J. Appl. Polym. Sci. 24 (2003) 683

E. M .Tyapochkin, E. I. Kozliak, J. Mol. Catal., A: Chem. 242 (2005) 1

G. Das, B. Sain, S. Kumar, Catal. Today 198 (2012) 228

J. C. Bricker, L. Laricchia, Top. Catal. 55 (2012) 1315

N. Lebedeva, N. Pavlycheva, O. Petrova, A. Vyugin, A. Kinchin, E. Parfenyuk, V. Mayzhlish, G. Shaposhnikov, Mendeleev Commun. 13 (2003) 237

A. W. Snow, in The Porphyrin Handbook. Phthalocyanines: Properties and Materials, K. M. Kadish, K. M. Smith, R. Guilard, Eds., Elsevier Science, Amsterdam, 2003, Ch. 17

A. A. Voronina, I. A. Kuzmin, A. S. Vashurin, G. P. Shaposhnikov, S. G. Pukhovskaya, O. A. Golubchikov, Russ. J. Gen. Chem. 84 (2014) 1777

M. R. Hoffmann, B. C. Lim, Environ. Sci. Technol. 13 (1979) 1406

M. R. Hoffmann, A. P. Hong, Sci. Total Environ. 64 (1987) 90

P.-S. K. Leung, M. R. Hoffmann, J. Phys. Chem. 93 (1989) 434

A. Andreev, V. Ivanova, L. Prahov, I. D. Schopov, J. Mol. Catal., A: Chem. 95 (1995) 197

H. Fischer, G. Shulz-Ekloff, D. Wörle, Chem. Eng. Technol. 20 (1997) 624

H. Fischer, G. Shulz-Ekloff, D. Wörle, Chem. Eng. Technol. 20 (1997) 462

S. A. Borisenkova, Pet. Chem. 31 (1991) 391

A. Vashurin, V. Maizlish, S. Pukhovskaya, A. Voronina, I. Kuzmin, N. Futerman, O. Golubchikov, O. Koifman, J. Porphyrins Phthalocyanines 19 (2015) 573

M. Hassanein, M. Abdo, S. Gerges, S. El-Khalafy, J. Mol. Catal., A: Chem. 287 (2008) 53

V. Iliev, A. Ilieva, J. Mol. Catal., A: Chem. 103 (1995) 147

V. Iliev, A. Ilieva, L. Bilyarska, J. Mol. Catal., A: Chem. 137 (1999) 15

N. Kuznetsova, N. Gretsova, V. Derkacheva, O. Kaliya, E. Lukyanets, J. Porphyrins Phthalocyanines 7 (2003) 147

A. S. Vashurin, S. G. Pukhovskaya, A. S. Semeikin, O. A. Golubchikov, Macro¬hetero-cycles 5 (2012) 72

W. J. Schutte, M. Sluyters-Rehbach, J. H. Sluyters, J. Phys. Chem. 97 (1993) 6069

E. V. Kudrik, S. V. Makarov, A. Zahl, R. van Eldik, Inorg. Chem. 42 (2003) 618

B. D. Berezin, Coordination compounds of porphyrins and phthalocyanines, Wiley, New York, 1981

J. K. Joseph, S. L. Jain, B. Sain, Ind. Eng. Chem. Res. 49 (2010) 6674

A. Voronina, I. Kuzmin, A. Vashurin, S. Pukhovskaya, N. Futerman, M. Shepelev, Eur. Chem. Bull. 3 (2014) 187

P.-S. K. Leung, M. R. Hoffmann, Environ. Sci. Tehnol. 22 (1988) 275

E. I. Kozlyak, A. S. Erokhin, A. K. Yatsimirski, React. Kinet. Catal. Lett. 33 (1987) 113

A. S Dubrovina, A. I. Malkova, L. M. Artem'eva, V. I. Tupikov, Russ. J. Phys. Chem. 62 (1988) 1904

D. M. Wagnerová, E. Schwertnerová, J. Vepřek-Šiška, Collect. Czech. Chem. Commun. 39 (1974) 1980

T. A. Fjellstedt, J. Schlesselman, J. Anal. Biochem. 80 (1977) 224

M. R. Ehsani, P. Mirjani, Al. Safadoost, Int. J. Chem. React. Eng. 11 (2013) 431.