Oxide coatings with immobilized Ce-ZSM5 as visible light photocatalysts Scientific paper

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Nikola Božović
Kristina Mojsilović
Srna Stojanović
Ljiljana Damjanović-Vasilić
Maria Serdechnova
Carsten Blawert
Mikhail L. Zheludkevich
Stevan Stojadinović
Rastko Vasilić


The preparation and properties of oxide coatings with immobilized ZSM-5 zeolite obtained by plasma electrolytic oxidation on aluminum support were investigated and discussed. Pure and Ce-exchanged ZSM-5 were immo­bilized on aluminum supports from a silicate-based electrolyte under ultra-low duty cycle pulsed direct current conditions. The obtained composite coatings were characterized with respect to their morphology, phase and chemical com­position, as well as photocatalytic activity and anti-corrosion properties. All mentioned properties of the obtained coatings were dependent on the proces­sing time. The coatings with Ce-exchanged ZSM-5 showed higher photocat­alytic activity and more effective corrosion protection than those with pure ZSM-5. The highest photocatalytic activity was observed for coatings pro­cessed for 30 min. It is suggested that the surface morphology, Ce-content and number of defects influenced the photocatalytic activity of the composite coat­ings.


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N. Božović, “Oxide coatings with immobilized Ce-ZSM5 as visible light photocatalysts: Scientific paper”, J. Serb. Chem. Soc., vol. 87, no. 9, pp. 1035–1048, Aug. 2022.
Physical Chemistry

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