Iron(III) complexes with ditopic macrocycles bearing crown-ether and bis(salicylidene) isothiosemicarbazide moieties: Scientific paper

Vladimir B. Arion; Oleg Palamarciuc; Sergiu Shova; Ghenadie Novitchi; Peter Rapta

doi:10.2298/JSC230607065A

PDF (2.18 MB) Supplementary Material (681 kB)

Published: Dec 25, 2023

Updated: 25.12.2023

DOI: https://doi.org/10.2298/JSC230607065A

Keywords:

iron(III) magnetism bi-compartmental ligand Mössbauer

Vladimir B. Arion

University of Vienna, Institute of Inorganic Chemistry, Währinger Strasse 42, 1090 Vienna, Austria

https://orcid.org/0000-0002-1895-6460

Oleg Palamarciuc

Moldova State University, A. Mateevici Street 60, MD-2009 Chisinau, Republic of Moldova

Sergiu Shova

Inorganic Polymers Department, "Petru Poni" Institute of Macromolecular Chemistry, Aleea Gr. Ghica Voda 41 A, Iasi 700487, Romania

https://orcid.org/0000-0002-1222-4373

Ghenadie Novitchi

CNRS-LNCMI, 38042 Grenoble Cedex, France

https://orcid.org/0000-0002-6109-6937

Peter Rapta

Institute of Physical Chemistry and Chemical Physics, Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava, Radlinského 9, SK-81237 Bratislava, Slovak Republic

Abstract

The main aims of this work were the synthesis and characterization of iron(III) complexes with a ditopic ligand H₂L consisting of a bis(salicylidene)isothiosemicarbazide moiety with a N₂O₂ binding site and a crown-ether (O₆) moiety. A series of high-spin iron(III) complexes, i.e., [Fe^IIILClBa(CH₃OH)(H₂O)_0.5(ZnCl₄)] (1), [Fe^IIILCl] (2), [Fe^IIIL(N₃)] (3) and [(Fe^IIIL)₂O] (4), were synthesized. The complexes were characterized by mass spectrometry, IR and UV–Vis spectroscopy, variable temperature (VT) magnetic susceptibility measurements, Mössbauer spectroscopy, single crystal X-ray diffraction and cyclic voltammetry.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

How to Cite

[1]

V. B. Arion, O. Palamarciuc, S. Shova, G. Novitchi, and P. Rapta, “Iron(III) complexes with ditopic macrocycles bearing crown-ether and bis(salicylidene) isothiosemicarbazide moieties: Scientific paper”, J. Serb. Chem. Soc., vol. 88, no. 12, pp. 1205–1222, Dec. 2023.

Issue

Vol. 88 No. 12 (2023): Theme issue honoring Professor Vukadin Leovac's 80th birthday

Section

Theme issue honoring Professor Vukadin Leovac's 80th birthday

This work is licensed under a Creative Commons Attribution 4.0 International License.

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution license 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

Funding data

Austrian Science Fund
Grant numbers I4729
Agentúra na Podporu Výskumu a Vývoja
Grant numbers APVV-19-0024
European Regional Development Fund
Grant numbers 313021BXZ1
Agenția Națională pentru Cercetare și Dezvoltare
Grant numbers 20.80009.5007.12

References

C. J. Van Staveren, J. Van Eerden, F. C. J. M. Van Veggel, S. Harkema, D. N. Reinhoudt, J. Am. Chem. Soc. 110 (1988) 4994 (https://doi.org/10.1021/ja00223a017)

F. C. J. M. Van Veggel, S. Harkema, M. Bos, W. Verboom, C. J. Van Staveren, G. J. Gerritsma, D. N. Reinhoudt, Inorg. Chem. 28 (1989) 1133 (https://doi.org/10.1021/ic00305a025)

F. C. J. M. van Veggel, W. Verboom, D. N. Reinhoudt, Chem. Rev. 94 (1994) 279 (https://doi.org/10.1021/cr00026a001)

D. N. Reinhoudt, A. R. Van Doorn, W. Verboom, J. Coord. Chem. 27 (1992) 91 (https://doi.org/10.1080/00958979209407946)

C. J. Van Staveren, D. E. Fenton, D. N. Reinhoudt, J. Van Eerden, S. Harkema, J. Am. Chem. Soc. 109 (1987) 3456 (https://doi.org/10.1021/ja00245a045)

C. J. van Staveren, D. N. Reinhoudt, J. van Eerden, S. Harkema, J. Chem. Soc., Chem. Commun. (1987) 974 (https://doi.org/10.1039/c39870000974)

D. M. Rudkevich, W. P. R. V. Stauthamer, W. Verboom, J. F. J. Engbersen, S. Harkema, D. N. Reinhoudt, J. Am. Chem. Soc. 114 (1992) 9671 (https://doi.org/10.1021/ja00050a064)

J. Halfpenny, R. W. H. Small, J. Chem. Soc., Chem. Commun. (1979) 879 (https://doi.org/10.1039/c39790000879)

V. B. Arion, V. C. Kravtsov, J. I. Gradinaru, Yu. A. Simonov, N. V. Gerbeleu, J. Lipkowski, J.-P. Wignacourt, H. Vezin, O. Mentré, Inorg. Chim. Acta 328 (2002) 123 (https://doi.org/10.1016/S0020-1693(01)00717-4)

M. T. Reetz, V. B. Arion, R. Goddard, Y. A. Simonov, V. Ch. Kravtsov, J. Lipkowski, Inorg. Chim. Acta 238 (1995) 23 (https://doi.org/10.1016/0020-1693(95)04661-R)

V. B. Arion, E. Bill, M. T. Reetz, R. Goddard, D. Stöckigt, M. Massau, V. Levitsky, Inorg. Chim. Acta 282 (1998) 61 (https://doi.org/10.1016/S0020-1693(98)00198-4)

V. B. Arion, J. P. Wignacourt, P. Conflant, M. Drache, M. Lagrenee, O. Cousin, H. Vezin, G. Ricart, W. Joppek, H.-W. Klein, Inorg. Chim. Acta 303 (2000) 228 (https://doi.org/10.1016/S0020-1693(00)00038-4)

V. B. Arion, V. C. Kravtsov, R. Goddard, E. Bill, J. I. Gradinaru, N. V. Gerbeleu, V. Levitschi, H. Vezin, Y. A. Simonov, J. Lipkowski, V. K. Bel’skii, Inorg. Chim. Acta 317 (2001) 33 (https://doi.org/10.1016/S0164-1212(00)00107-2)

J. Costes, F. Dahan, G. Novitchi, V. Arion, S. Shova, J. Lipkowski, Eur. J. Inorg. Chem. (2004) 1530 (https://doi.org/10.1002/ejic.200300486)

M. T. Reetz, V. B. Arion, R. Trültzsch, H. Buschmann, E. Cleve, Chem. Ber. 128 (1995) 1089 (https://doi.org/10.1002/cber.19951281106)

J.-C. Moutet, E. Saint-Aman, E.-M. Ungureanu, V. Arion, N. Gerbeleu, M. Revenco, Electrochim. Acta 46 (2001) 2733 (https://doi.org/10.1016/S0013-4686(01)00482-0)

G. M. Sheldrick, Acta Crystallogr., A 64 (2008) 112 (https://doi.org/10.1107/S0108767307043930)

M. N. Burnett,C. K. Johnson, ORTEP-III: Oak Ridge Thermal Ellipsoid Plot Program for Crystal Structure Illustrations, Oak Ridge National Laboratory, Oak Ridge, TN, 1996 (https://doi.org/10.2172/369685)

G. A. Bain, J. F. Berry, J. Chem. Educ. 85 (2008) 532 (https://doi.org/10.1021/ed085p532)

O. Kahn, Molecular Magnetism, Wiley-VCH, New York, 1993 ISBN 0471188787, 9780471188384

M. A. Yampol’skaya, S. G. Shova, N. V. Gerbeleu, V. K. Bel’skii, Yu. A. Simonov, Zh. Neorg. Khim. 27 (1982) 2551

K. S. Murray, Coord. Chem. Rev. 12 (1974) 1 (https://doi.org/10.1016/S0010-8545(00)80384-7)

J. S. Griffith, Mol. Phys. 8 (1964) 213 (https://doi.org/10.1080/00268976400100251)

M. Gerloch, J. Lewis, F. E. Mabbs, A. Richards, J. Chem. Soc. A (1968) 112 (https://doi.org/10.1039/J19680000112)

M. Gerloch, J. Lewis, F. E. Mabbs, A. Richards, Nature 212 (1966) 809 (https://doi.org/10.1038/212809a0)

M. Gerloch, F. E. Mabbs, J. Chem. Soc., A (1967) 1598 (https://doi.org/10.1039/J19670001598)

S. Hayami, S. Nomiyama, S. Hirose, Y. Yano, S. Osaki, Y. Maeda, J. Radioanal. Nucl. Chem. 239 (1999) 273 (https://doi.org/10.1007/BF02349496)

T. H. Moss, A. J. Bearden, W. S. Caughey, J. Chem. Phys. 51 (1969) 2624 (https://doi.org/10.1063/1.1672387)

G. Feher, P. L. Richards, in Magnetic Resonance in Biological Systems, Elsevier, Amsterdam, 1967, pp. 141−144 (https://doi.org/10.1016/B978-1-4832-1333-0.50019-7)

S. G. Shova, M. A. Yampol’skaya, B. G. Zemskov, N. V. Gerbeleu, K. I. Turta, I. N. Ivleva, Zh. Neorg. Khim. 30 (1985) 2309

M. Blume, Phys. Rev. Lett. 18 (1967) 305 (https://doi.org/10.1103/PhysRevLett.18.305)

A. V. Ablov, V. I. Gol’danskii, K. I. Turta, R. A. Stukan, V. V. Zelentsov, E. V. Ivanov, N. V. Gerbeleu, Dokl. Akad. Nauk SSSR 196 (1971) 1101

N. V. Gerbeleu, K. I. Turta, V. M. Canic, V. M. Leovac, V. B. Arion, Koord. Khim. 6 (1980) 446

J.-P. Costes, F. Dahan, F. Dumestre, J. Modesto Clemente-Juan, J. Garcia-Tojal, J.-P. Tuchagues, Dalton Trans. (2003) 464 (https://doi.org/10.1039/b210950f)

S. M. Gorun, S. J. Lippard, Inorg. Chem. 30 1991 1625 (https://doi.org/10.1021/ic00007a038).

Iron(III) complexes with ditopic macrocycles bearing crown-ether and bis(salicylidene) isothiosemicarbazide moieties Scientific paper