Synthesis, characterization and antimicrobial activity of isothiocyanato Fe(III) Girard's T hydrazone complex

Main Article Content

Božidar Čobeljić
Andrej Pevec
Zvonko Jagličić
Milica R. Milenković
Iztok Turel
Dušanka Radanović
Marina Milenković
Katarina Anđelković

Abstract

Isothiocyanato Fe(III) complex with (E)-N,N,N-trimethyl-2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray analysis. Octahedral geometry of Fe(III) complex consist of deprotonated form of hydrazone ligand coordinated through pyridine nitrogen, azomethine nitrogen and carbonyl oxygen atoms and three isothiocyanato ligands in the rest coordination places. The measured effective magnetic moment for Fe(III) complex corresponds to high spin Fe(III) ion. The hydrazone ligand and its Fe(III) complex showed lower activity against the tested microbial strains than standard antimicrobial drugs

Article Details

How to Cite
[1]
B. Čobeljić, “Synthesis, characterization and antimicrobial activity of isothiocyanato Fe(III) Girard’s T hydrazone complex”, J. Serb. Chem. Soc., vol. 83, no. 12, pp. 1327-1337, Dec. 2018.
Section
Inorganic Chemistry

References

L. N. Suvarapu, Y. K. Seo, S. O. Baek, V. R. Ammireddy, Eur. J. Chem. 9 (2012) 1288 (http://dx.doi.org/10.1155/2012/534617)

Lj. S. Vojinović-Ješić, S. B. Novaković, V. M. Leovac, V. I. Češljević, J. Serb. Chem. Soc. 77 (2012) 1129 (http://dx.doi.org/10.2298/JSC120704083V)

B. Čobeljić, M. Milenković, A. Pevec, I, Turel, M. Vujčić, B. Janović, N. Gligorijević, D. Sladić, S. Radulović, K. Jovanović, K. Anđelković, J. Biol. Inorg. Chem. 21 (2016) 145 (http://dx.doi.org/10.1007/s00775-015-1315-x)

M. R. Milenković, B. Čobeljić, K. Anđelković, I. Turel, Eur. J. Inorg. Chem. 2018 (2018) 838 (http://dx.doi.org/10.1002/ejic.201701387)

B. Čobeljić, A. Pevec, S. Stepanović, V. Spasojević, M. Milenković, I. Turel, M. Swart, M. Gruden-Pavlović, K. Adaila, K. Anđelković, Polyhedron 89 (2015) 271 (http://dx.¬doi.org/10.1016/j.poly.2015.01.024)

B. Čobeljić, A. Pevec, S. Stepanović, M. R. Milenković, I. Turel, M. Gruden, D. Radanović, K. Anđelković, Struct. Chem. accepted (https://doi.org/10.1007/s11224-018-1155-8)

K. Anđelković, M. R. Milenković, A. Pevec, I. Turel, I. Z. Matić, M. Vujčić, D. Sladić, D. Radanović, G. Brađan, S. Belošević, B. Čobeljić, J. Inorg. Biochem. 174 (2017) 137 (http://dx.doi.org/10.1016/j.jinorgbio.2017.06.011)

O. Kahn, Molecular Magnetism, VCH Publishing, Orsay France (1993) p. 2 (ISBN: 0471188387)

Z. Otwinowsky, W. Minor, Methods Enzymol. 276 (1997) 307 (https://doi.org/10.1016/-S0076-6879(97)76066-X)

L. J. Farrugia, J. Appl. Crystallogr. 32 (1999) 837 (http://dx.doi.org/doi:10.1107/-S0021889899006020)

A. Altomare, G. Cascarano, C. Giacovazzo, A. Guagliardi, J. Appl. Crystallogr. 26 (1993) 343 (http://dx.doi.org/https://doi.org/10.1107/S0021889892010331)

G. M. Sheldrick, Acta. Crystallogr. C71 (2015) 3 (https://doi.org/10.1107/S205322-9614024218)

K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, fourth ed., Wiley-Interscience, New York, 1986, p. 283 (https://doi.org/10.1002/¬bbpc.-198800131)

O. V. Palamarciuc, P. N. Bourosh, M. D. Revenco, J. Lipkowski, Y. A. Simonov, R. Clérac, Inorg. Chim. Acta 363 (2010) 2561 (https://doi.org/10.1016/j.ica.2010.04.027)

C. Janiak, J. Chem. Soc., Dalton Trans. (2000) 3885 (http://dx.doi.org/10.1039/B003010O)

T. Steiner, Angew. Chem. Int. Ed. 41 (2002) 48 (https://doi.org/10.1002/1521-3773(20020104)41:1<48::AID-ANIE48>3.0.CO;2-U)

L. J. Farrugia, J. Appl. Crystallogr. 45 (2012) 849 (https://doi.org/10.1107/S0021889¬812029111)

C. F.Macrae, P. R. Edgington, P. McCabe, E. Pidcock, G. P. Shields, R. Taylor, M. Towler, J. van de Streek, J. Appl. Crystallogr. 39 (2006) 453 (http://dx.doi.org/10.1107/¬S002188980600731X)

F. E. Mabbs, D. J. Machin, Magnetism and Transition Metal Complexes, Dover Publications, Inc. Mineola, New York (1973) (ISBN: 0486462846)

N. W. Ashcroft, N. D. Mermin, Solid State Physics, Saunders College Publishing, USA, (1976) (ISBN: 0030839939)

J. M. D. Coey, Magnetism and magnetic materials, Cambridge University Press, 2010 (ISBN: 978-0-521-81614-4)

Most read articles by the same author(s)